Bis[3-dimethylamino-1-(pyridin-2-yl)prop-2-en-1-one-κ2 N 1,O]tris(nitrato-κ2 O,O)gadolinium(III) ethanol disolvate
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چکیده
In the title compound, [Gd(NO(3))(3)(C(10)H(12)N(2)O)(2)]·2C(2)H(5)OH, the Gd(III) ion and one nitrate anion are located on a twofold rotation axis. The Gd(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-anti-prismatic geometry. In the crystal, the components are linked by O-H⋯O hydrogen bonds. The ethanol solvent mol-ecule is disordered over two positions in a ratio 0.615 (16):0.385 (16).
منابع مشابه
Bis[3-dimethylamino-1-(2-pyridyl)prop-2-en-1-one-κ2 N 2′,O]tris(nitrato-κ2 O,O′)praseodymium(III)
In the title compound, [Pr(NO(3))(3)(C(10)H(12)N(2)O)(2)], the Pr(III) ion is ten-coordinated by two N and two O atoms from two bidentate 3-(dimethyl-amino)-1-(2-pyrid-yl)prop-2-en-1-one ligands and by six O atoms from three nitrate anions in a distorted bicapped square-anti-prismatic geometry. An extensive three-dimensional network of weak inter-molecular C-H⋯O hydrogen bonds consolidates the ...
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